Carbon supported phosphoric acid (H3PO4/C) was found to be a more productive catalyst for the gas-phase synthesis of the diesel fuel additive/substitute oxymethylene ethers (OME) as compared to benchmark zeolite catalysts. In this contribution, the performance of catalysts H3PO4/C and related H2PO4−/C and HPO42−/C materials in OME synthesis from methanol and formaldehyde is described.
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